Ferrocene-derivatized large pore size mesocellular carbon foam (Fe-MCF-C) has been synthesized using divinylbenzene as a carbon source and mesocellular silica foam as a hard template. Cyclic voltammetric studies demonstrate a relatively faster electron transfer rate of Fe-MCF-C in K 3 Fe(CN) 6 /1 M
Soft-template synthesized ordered mesoporous carbon counter electrodes for dye-sensitized solar cells
β Scribed by Easwaramoorthi Ramasamy; Jinyoung Chun; Jinwoo Lee
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 413 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0008-6223
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β¦ Synopsis
Ordered mesoporous carbon (OMC) with a high surface area ($1575 m 2 /g) and bimodal pores (2.5 and 6.1 nm) was synthesized using a soft-template method employing triblock copolymer F127 as the structure directing agent and then applied as a low-temperature processable counter electrode for dye-sensitized solar cell (DSSC). The OMC counter electrode-based DSSC shows an energy conversion efficiency of 7.46%, whereas that of a Vulcan counter electrode is 4.30%. Electrochemical impedance spectroscopy analysis reveals decreased charge transfer resistance at the OMC counter electrode-electrolyte interface, thus improved fill factor and energy conversion efficiency.
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