✦ LIBER ✦

Sodium Nitrite-Catalyzed Oxybromination of Aromatic Compounds and Aryl Ketones with a Combination of Hydrobromic Acid and Molecular Oxygen under Mild Conditions

✍ Scribed by Guofu Zhang; Renhua Liu; Qing Xu; Lixin Ma; Xinmiao Liang

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 92 KB
Volume: 348
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200505495

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A novel and efficient catalytic system for the oxybromination of aromatic compounds and aryl ketones utilizing a combination of aqueous hydrobromic acid and molecular oxygen in the presence of sodium nitrite under mild conditions has been developed. The newly developed catalytic system utilizes cheap and readily available reactants, exhibits high bromine atom economy and releases only innocuous water as the by‐product.

📜 SIMILAR VOLUMES

Sodium Nitrite Catalyzed Oxybromination

Sodium Nitrite Catalyzed Oxybromination of Aromatic Compounds and Aryl Ketones with a Combination of Hydrobromic Acid and Molecular Oxygen under Mild Conditions.

✍ Guofu Zhang; Renhua Liu; Qing Xu; Lixin Ma; Xinmiao Liang 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

Trace Water-Promoted Oxidation of Benzyl

Trace Water-Promoted Oxidation of Benzylic Alcohols with Molecular Oxygen Catalyzed by Vanadyl Sulfate and Sodium Nitrite under Mild Conditions

✍ Zhongtian Du; Hong Miao; Hong Ma; Zhiqiang Sun; Jiping Ma; Jie Xu 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB 👁 2 views

## Abstract magnified image An inexpensive catalytic system consisting of vanadyl sulfate and sodium nitrite was developed for the oxidation of benzylic alcohols with molecular oxygen under mild conditions. Benzyl alcohols with various substitutions were efficiently converted to their correspondin