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Sodium N-bromo-4-chlorobenzenesulfonamidate sesquihydrate

✍ Scribed by Gowda, B. Thimme ;Kožíšek, Jozef ;Tokarčík, Miroslav ;Fuess, Hartmut

Book ID
104491024
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
660 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the structure of the title compound, Na + ÁC 6 H 4 Br-ClNO 2 S À Á1.5H 2 O, which crystallizes with two cations, two anions and three water molecules in the asymmetric unit, the sodium ions show octahedral coordination by three O atoms of water molecules and by three sulfonyl O atoms of three different N-bromobenzenesulfonamide anions. The S-N distances [1.574 (5) and 1.579 (4) A ˚] are consistent with an S N double bond. The crystal structure is stabilized by O-HÁ Á ÁBr, O-HÁ Á ÁN, O-HÁ Á ÁO and C-HÁ Á ÁBr hydrogen bonds.

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