The solid solution Na,+ar,(P0,),\_,( ),has been investigated by \*)Na NMR. The parameters of the quadrupole tensor of the Na( 1) positions in NaZr2(P04), are yq= 1.2kO.l MHz and ~=0.04+0.04. Those for the Na( 1) and Na(2) sites in Na,Zr,(SiO,), are found to be Na( 1): vq= 1.04+0.1 MHz, ~=0.84?0.7; N
✦ LIBER ✦
Sodium motion in the Nasicon related Na1+xZr2−xInx(PO4)3 solid solution: An NMR study
✍ Scribed by F. Cherkaoui; G. Villeneuve; C. Delmas; P. Hagenmuller
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 520 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-4596
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Several compounds of the (Na 1؊x Li x )CdIn 2 (PO 4 ) 3 solid solution were synthesized by a solid-state reaction in air, and pure alluaudite-like compounds were obtained for x ؍ 0.00, 0.25, and 0.50. X-ray Rietveld re5nements indicate the occurrence of Cd 2؉ in the M(1) site, and of In 3؉ in the