Sodium Controlled Selective Reactivity of Protonated Deoxy-Oligonucleotides in the Gas Phase
✍ Scribed by Helga Dögg Flosadóttir; Michal Stano; Oddur Ingólfsson
- Book ID
- 108158501
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 595 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1044-0305
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The energies of protonation and Na' cationization of glycine (GLY) and its (GLY -H + Na) salt in the gas phase were calculated using ab initio calculations. The proton affinity of GLY, valued at the MP2/6-31G\*//3-21G level, is 937 kJ mol-'. The amino function is confirmed to be the most favourable