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SnCl4-Promoted Rearrangement of 2,3-Epoxy Alcohol Derivatives: Stereochemical Control of the Reaction.

✍ Scribed by Yasuyuki Kita; Satoshi Matsuda; Ryoko Inoguchi; Jnaneshwara K. Ganesh; Hiromichi Fujioka


Publisher
John Wiley and Sons
Year
2005
Weight
36 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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A number of 2,3-epoxy alcohol derivatives (1-16), obtained either as racemates or through the Sharpless asymmetric epoxidation reaction, were studied on a Chiralcel OD column. Nearly all compounds exhibit good enantioselective resolution on this chiral support. The order of elution of enantiomers is