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SN2' reactions of cis-3,4-dichlorocyclobutene

✍ Scribed by Kirmse, Wolfgang; Scheidt, Friedrich; Vater, Hans Joachim


Book ID
121273458
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
269 KB
Volume
100
Category
Article
ISSN
0002-7863

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The thermally induced ring opening of 1 and 5 proceeds with found, a behaviour that corresponds with the known photochemistry of cyclobutenes. A surprising reaction was high stereospecifity in a conrotatory fashion in agreement with the Woodward-Hoffmann rules. Upon flash pyrolysis of found if 1 and