✦ LIBER ✦
SN2 or Electron Transfer?? A new technique discriminates the mechanisms of oxidative addition of alkyl halides to corrinato- and porphyrinatocobalt(I)
✍ Scribed by De-Ling Zhou; Peristera Walder; Rolf Scheffold; Lorenz Walder
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- German
- Weight
- 921 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
The following abbreviations are used: Cbl = cobalamin [le]; for convenience, we use 'Cby' instead of Cby(MeO), for heptamethyl cobyrinate (cf Cby = cobyric acid [le]), [Co(oep)] = (2,3,7,8,12,13,17,18-octaethy1porphyrinato)cobalt [If], [Co(tpp)] = (5,10,15,20-tetraphenylporphyrinato)cobalt [If]; [CoL] = any of the Co complexes under investigation; mechanism abbreviations are explained in Scheme 1. ' ) ' ) ' )