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SmI2-promoted conjugate reduction of α,β-unsaturated esters and ketones studied in comparison with Mukaiyama-Michael reaction of ketene silyl acetal

✍ Scribed by Yukihiro Fujita; Shunichi Fukuzumi; Junzo Otera

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 155 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00322-5

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✦ Synopsis

SmI2-promoted conjugate reduction of ~-unsaturated esters and ketones txoceeds in a manner quite similar to Mukaiyama-Michael reaction of ketene silyl acetal. The more substituted

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