𝔖 Bobbio Scriptorium
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Small ring compounds XX cyclopropyl radicals

✍ Scribed by Tatsuya Shono; Mitsumasa Akashi; Ryohei Oda

Book ID
108385227
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
231 KB
Volume
9
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Properties of small ring free radicals.
Properties of small ring free radicals. I. Thermal decompositions of α-substituted cyclopropyl percarboxylates
✍ R.A. Wolf; W. Rozich 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 252 KB

Several experimental techniques have evolved to differentiate between two possible mechanisms of the thermal decomposition of oeroxv esters. These two mechanisms, the concerted and the non-concerted (Scheme I), have been investi-1 aated bv studvinq activation parameters , the effect on rates of deco

The chemistry of small ring compounds. P
The chemistry of small ring compounds. Part 43. Synthesis of 1-substituted cyclopropyl sulfides
✍ R. Jorritsma; H. Steinberg; Th. J. de Boer 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 874 KB

## Abstract 1‐Hydroxy‐ and 1‐halocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the α‐position can be transformed into 1‐substituted cyclopropyl sulfides with a variety of nucleophiles. This means tha

The chemistry of small ring compounds. P
The chemistry of small ring compounds. Part 44. Solvolysis of cyclopropyl sulfides and ethers
✍ R. Jorritsma; H. Steinberg; Th. J. de Boer 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 684 KB

## Abstract 1‐Chlorocyclopropyl methyl ether and the corresponding sulfide are methanolysed without any rupture of the three‐membered ring. The solvolysis of 1‐halocyclopropyl sulfides has been studied kinetically and takes place __via__ an __S__~N~1 mechanism. Methyl substituents in the cyclopropy