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Small-Ring Compounds. III. Synthesis of Cyclobutanone, Cyclobutanol, Cyclobutene and Cyclobutane

✍ Scribed by Roberts, John D.; Sauer, Charles W.

Book ID
119993156
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
612 KB
Volume
71
Category
Article
ISSN
0002-7863

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✦ Synopsis

This compound must be analyzed immediately since it is hydrolyzed rapidly by the moisture in the air. One sample which was allowed to stand for two days had only 9.73% nitrogen. This same sample was allowed to stand for several weeks and a t that time had only 5.0iYo nitrogen.

An attempt to prepare a picrate of this compound gave 'only the picrate of methylamine, m. p. and mixed m. p. 209-21 1 uncor .

Anal. Calcd. for

πŸ“œ SIMILAR VOLUMES

Theoretical Study of Small Ring Compound
Theoretical Study of Small Ring Compounds. I. Cyclopropene and Cyclobutene
✍ J. M. AndrΓ©; M. Cl. AndrΓ©; G. Leroy πŸ“‚ Article πŸ“… 2010 πŸ› Wiley (John Wiley & Sons) βš– 504 KB

In this work, we report an all-electron SCF-LCAO-MO computation for the ground-state wave functions of the cyclopropene and cyclobutene molecules. The study of the ethylenic bond shows some delocalization of d i k e electrons to the methylene groups. Experimental results are discussed. On ddcrit un