Small Peptide-Catalyzed Enantioselective Addition of Ketones to Nitroolefins
✍ Scribed by Yongmei Xu; Weibiao Zou; Henrik Sundén; Ismail Ibrahem; Armando Córdova
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 126 KB
- Volume
- 348
- Category
- Article
- ISSN
- 1615-4150
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract A highly enantioselective Michael reaction of aromatic ketones with nitroolefins was accomplished in the presence of a chiral bifunctional primary amine–thiourea catalyst and 4‐nitrobenzoic acid as the co‐catalyst; the corresponding adducts were obtained in excellent enantioselectivitie
## Abstract The tripeptide D‐Pro‐Pro‐Glu‐NH~2~ is highly efficient for the title reactions.