It is sho)vn that the changes in the non-mdiativc decay rate of dilute aromatic vapors, following excitation of higher-lying singlet states, can be related to the dependence of vibrational level distribution (in St) upon the initially excited singlet states. The excitation energy dependence of radia
Small molecule characteristics of the radiative decay of highly excited states of some large molecules
โ Scribed by P. Wannier; P.M. Rentzepis; J. Jortner
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 470 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Resonance fluorescence characterized by anomalously long radiative lifetime was observed from the skcond excited singlet state of the "isolated" 3.4 benzpyrene molecule, confkmiag theoretical predictions for strong ROR adiabatic coupling between two close lying electronic states of a large molecule. This communication is concerned with the features of the radiative decay of the second excited singlet state, $;, of la.+, isolated (collision free) aromatic
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