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Small chelators and the nature of the metal ion in site specificity of OH° damage

✍ Scribed by Dan Gelvan; Paul Saltman

Book ID
113385423
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
126 KB
Volume
9
Category
Article
ISSN
0891-5849

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✍ Hu Peifeng; Curt Sorensen; Michael L. Gross 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 583 KB

Aromatic side chains on amino acids influence the fragmentations of cationic complexes of doubly charged metal ions and singly deprotonated peptides. The metal ion interacts with an aromatic side chain and binds to adjacent amide nitrogens. When fragmentation occurs, this bonding leads to the format