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Small-angle neutron scattering evidence for a bicontinuous structure in a microemulsion containing equal volumes of oil and water

โœ Scribed by A. De Geyer; J. Tabony


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
431 KB
Volume
124
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Small-angle neutron scattering has been used to determine whether or not a microemulston, contaming equal volumes of oil and water, has a bicontinuous structure. The spectrum. from the interfacial layer of surfactant and co-surfactant. shows the presence of distances both longer and shorter than those occurrmg in a closed shell. Thus excludes the possibihty that the microemulsion structure is a dispersion of disconnected, albeit closely packed, droplets of equal size, but is consistent with the formation of connections between oil and water domains such as would occur in a locally ordered bicontinuous structure.


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A multicomponent oil-in-water microemulsion containing CTAB (C16H33NMe3Br), n-octane. I-butanol. NaBr, and D20 has been studied by small-angle neutron scattering at several temperatures The size of the microemulsion droplets was found to be independent of temperature. Correlation lengths for the cri