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Slow spin relaxation induced by magnetic field in [NdCo(bpdo)(H 2 O) 4 (CN) 6 ]⋅3H 2 O

✍ Scribed by Vrábel, P; Orendáč, M; Orendáčová, A; Čižmár, E; Tarasenko, R; Zvyagin, S; Wosnitza, J; Prokleška, J; Sechovský, V; Pavlík, V; Gao, S

Book ID
120594172
Publisher
Institute of Physics
Year
2013
Tongue
English
Weight
491 KB
Volume
25
Category
Article
ISSN
0953-8984

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Slow Magnetic Relaxation of [Et3NH]2Mn(C
Slow Magnetic Relaxation of [Et3NH]2Mn(CH3CN)4(H2O)2] [Mn10O4(biphen)4Br12] (biphen=2,2′-biphenoxide) at Very Low Temperature
✍ A.L. Barra; Andrea Caneschi; Dante Gatteschi; David P. Goldberg; Roberta Sessoli 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 134 KB

The high-5eld EPR spectra of a mixed valence cluster compound of formula [Et 3 NH] 2 [Mn(CH 3 CN) 4 (H 2 O) 2 ] [Mn 10 O 4 (biphen) 4 Br 12 ] con5rm that the high-spin ground state (S ‫؍‬ 12) of the cluster has a negative zero-5eld splitting, D ‫؊؍‬ 0.037(1) cm ؊1 . The reversal of the magnetization