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Slow Metastable Dissociation of Chemically Activated Adduct Ions. The Fourier Transform Ion Cyclotron Resonance Analog of the MIKES Experiment

✍ Scribed by Audier, H. E.; McMahon, T. B.


Book ID
126100727
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
759 KB
Volume
116
Category
Article
ISSN
0002-7863

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An accurate gas-phase acidity for germane (enthalpy scale, equivalent to the proton affinity of GeH3 (-)), Ξ”H acid (o)(GeH4) = 1502.0 Β± 5.1 kJ mol(-1), is obtained by constructing a consistent acidity ladder between GeH4, and H2S by using Fourier transform-ion cyclotron resonance spectrometry, and 0