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Slow inversion of stereoisomers of cyclic GABA analogues

✍ Scribed by Roman Gancarz; Rafał Latajka; Agnieszka Halama; Paweł Kafarski

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
602 KB
Volume
38
Category
Article
ISSN
0749-1581

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✦ Synopsis

In 31 P NMR spectra of derivatives of 1-amino-and 1-hydroxypiperid-4-ylphosphonic acids, fully reversible conformational equilibria in aqueous and methanolic solutions were observed. Depending on the pH of the medium and temperature, one or two phosphorus signals were observed indicating slow conformational ring interconversion under specific conditions.

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