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Skeletal rearrangements of 2-pyrones involving 1,5-sigmatropic hydrogen shifts

โœ Scribed by Pirkle, William H.; Seto, Herbert G.; Turner, Walter V.


Book ID
125989728
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
266 KB
Volume
92
Category
Article
ISSN
0002-7863

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The rate constants for the 1,3-and 1,Mgmatropic hydrogen shifts of the phot&Fries rearranged intermediates of phenyl acetate produced by laser flash photolysis at 266 nm were directly measured in several solvents. The rate constant for the 1,3hydrogen shift (3.6 s-l) was faster than that for the l&s