Size-tuneable synthesis of photoconducting poly-(3-hexylthiophene) nanofibres and nanocomposites
✍ Scribed by Yichen Zhao; Abhilash Sugunan; David B. Rihtnesberg; Qin Wang; Muhammet S. Toprak; Mamoun Muhammed
- Book ID
- 112182355
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 659 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1862-6351
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## Abstract New functionalized poly(3‐hexylthiophene)s (P3HT) have been designed and synthesized with the aim of increasing the dispersion of carbon nanotubes (CNT) in solutions and in thin films of semiconducting polymers. Dispersion in solution has been assessed by sedimentation tests while the t
## Abstract **Summary:** The polymerization of 2‐bromo‐3‐hexyl‐5‐iodothiophene (**1**) with isopropylmagnesium chloride and Ni(dppp)Cl~2~ was quenched with 5 M hydrochloric acid instead of water to yield head‐to‐tail poly(3‐hexylthiophene) (HT‐P3HT) with a very low polydispersity. The $\overline M