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Size-dependent melting point depression of nanostructures: Nanocalorimetric measurements

โœ Scribed by Zhang, M.; Efremov, M.; Schiettekatte, F.; Olson, E.; Kwan, A.; Lai, S.; Wisleder, T.; Greene, J.; Allen, L.

Book ID
111893115
Publisher
The American Physical Society
Year
2000
Tongue
English
Weight
590 KB
Volume
62
Category
Article
ISSN
1098-0121

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For the first time, the latent heat of fusion DH m for Sn particles formed by evaporation on inert substrate with radii ranging from 5 to 50 nm has been measured directly using a novel scanning nanocalorimeter. A particle-size-dependent reduction of DH m has been observed. An "excluded volume" is in