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Six Supramolecular Coordination Complexes Containing Phenoxy Pyrazole-Carboxyl Ligands

✍ Scribed by Shen, Lei; Li, Wu-Xiang; Xia, Qiu-Jie; Yang, Jie; Liu, Yun; Ji, Cheng; Wu, Chun-Yan; Zhai, Yong-Shai; Yang, Gao-Wen; Li, Qiao-Yun

Book ID
125362982
Publisher
Springer
Year
2013
Tongue
English
Weight
891 KB
Volume
43
Category
Article
ISSN
1572-8854

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✍ Paul K. Baker; Marit van Kampen; Christina Roos; Julia Spaeth πŸ“‚ Article πŸ“… 1994 πŸ› Springer 🌐 English βš– 352 KB

Equimolar quantities of [MI2(CO)3(NCMe)2 ] (M = Mo or W) and C3H4N2 (pyrazole) react in CH2C12 at room temperature to give the iodo-bridged dimers [M(#-I)(CO)3(C:~H~N2)]2 (I) and (2). Two equivalents of C3H4N 2 react with [MIz(CO)a(NCMe)2] (M = Mo or W) to give the bis(pyrazole) complexes [MIz(CO)3(