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Six novel transition-metal phosphite compounds, with structure related to yavapaiite: Crystal structures and magnetic and thermal properties of AI[MIII(HPO3)2] (A=K, NH4, Rb and M=V, Fe)

✍ Scribed by Hamchaoui, Farida; Alonzo, Véronique; Venegas-Yazigi, Diego; Rebbah, Houria; Le Fur, Eric

Book ID: 118267253
Publisher: Elsevier Science
Year: 2013
Tongue: English
Weight: 882 KB
Volume: 198
Category: Article
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2012.10.007

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Two Novel Transition-Metal Phosphite Compounds with 4-, 6- and 12-Membered Rings: Hydrothermal Syntheses, Crystal Structures and Magnetic Properties of Na2[M(HPO3)2] (M: Fe, Co).

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## Abstract Two transition‐metal phosphites, Na~2~[M(HPO~3~)~2~] (M = Fe, Co) with a new structure type have been synthesised under mild hydrothermal conditions and the solid‐state structures have been elucidated by single‐crystal X‐ray diffraction studies. The structures are of a new type with the