Eight new C 21 steroidal glycosides, named wilfosides A -H (1 -8, resp.), along with one known compound wilfoside KIN (9), were isolated from the roots of Cynanchum wilfordii. The structures of the new glycosides were determined on the basis of spectroscopic analysis, including 1D-and 2D-NMR, and ES
Six New C21 Steroidal Glycosides from Cynanchum bungeiDecne
✍ Scribed by Hao Gan; Wen-Juan Xiang; Lei Ma; Li-Hong Hu
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- German
- Weight
- 208 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Six new C~21~ steroidal glycosides 1–6 were isolated from the stem parts of Cynanchum bungei Decne. The structures of the new glycosides were determined on the basis of spectroscopic analysis, including 1D‐ and 2D‐NMR and HR‐ESI‐MS techniques as well as by comparison of their spectral data with those of related compounds.
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## Abstract magnified image Four new C~21~ steroidal glycosides with an acyl group at C(12) and a straight sugar chain at C(3), namely auriculosides I–IV (**1**–**4**, resp.), along with seven known steroidal derivatives, were isolated from the roots of __Cynanchum auriculatum__ Royle ex Wight. Th
## Abstract magnified image Two new glycosides, (3__β__,8__β__,9__α__,16__α__,17__α__)‐14,16__β__ : 15,20__α__:18,20__β__‐triepoxy‐16__α__,17__α__‐dihydroxy‐14‐oxo‐13,14 : 14,15‐disecopregna‐5,13(18)‐dien‐3‐yl __α__‐cymaropyranosyl‐(1→4)‐__α__‐digitoxopyranosyl‐(1→4)‐__α__‐oleandropyranoside (**1*
## Abstract Three new C~21~ steroidal glycosides with a cinnamoyl group at C(12) and a 2‐methylbutanoyl group at C(20), and a straight sugar chain at C(3), namely cyanoauriculosides C–E (**1**–**3**, resp.), together with three known steroidal derivatives, were isolated from the roots of __Cynanchu