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S(IV) Autoxidation in Atmospheric Liquid Water: The Role of Fe(II) and the Effect of Oxalate

✍ Scribed by Irena Grgićc; Marjeta Pozničc; Mirko Bizjak


Book ID
110232506
Publisher
Springer Netherlands
Year
1999
Tongue
English
Weight
103 KB
Volume
33
Category
Article
ISSN
0167-7764

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The role of Fe(II) species on the oxidat
✍ J.M. Santana-Casiano; M. González-Dávila; F.J. Millero 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 227 KB

The oxidation of Fe(II) at nanomolar levels with O 2 , H 2 O 2 and their mixtures has been studied and a kinetic model has been applied to describe the experimental results. A first order pH dependence is obtained when the H 2 O 2 controls the oxidation, due to the large contributions of FeOH + and