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Site selectivity in the reactions of 1,3-dipoles with norbornadiene derivatives

✍ Scribed by D. Cristina; M. De Amici; C. De Micheli; R. Gandolfi

Book ID: 108373872
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 853 KB
Volume: 37
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)92451-2

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The Diels-Alder reaction of the title triene occurred at the site of C-3-C-6 rather than of intuitively favored C-l-C-4, as the result of the prevailing steric effect over the orbital effect.