## Abstract The metastable ions of Fe^+^ complexes of aldimines R^1^NCHR^2^ exhibit a unique behaviour in that sequential loss of olefin/H^2^ follows two distinct pathways: one corresponds to the familiar pattern of double remote functionalization, involving either alkyl chain R^1^ and R^2^. In ad
✦ LIBER ✦
Site-Selectivity in the Fe+-Mediated CH/CC Bond Activation of Aldimines Short Communication
✍ Scribed by Tilmann Prüsse; Helmut Schwarz
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- German
- Weight
- 203 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0018-019X
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The thermal ion-molecule reactions NiX þ þ CH 4 ! Ni(CH 3 ) þ þ HX (X ¼ H, CH 3 , OH, F) have been studied by mass spectrometric methods, and the experimental data are complemented by density functional theory (DFT)-based computations. With regard to mechanistic aspects, a rather coherent picture em