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Site Selective .sigma.-Bond Metathesis Reactions of Sc(CD3)2+ with [2,2-D2]Propane, [1,1,1,4,4,4-D6]-n-Butane, and [2-D]Isobutane

✍ Scribed by Crellin, Kevin C.; Geribaldi, Serge; Beauchamp, J. L.


Book ID
126866428
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
390 KB
Volume
13
Category
Article
ISSN
0276-7333

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## Abstract Using commercially available paraformaldehyde–d~2~, the subject compounds were synthesized with unlabeled reactants and ordinary solvents. The 2,2–dinitropropane–1,3‐diol–1,1,3,3–d~4~ (ADIOL–d~4~) precursor was produced in greater than 99% isotopic purity with aqueous depolymerized para