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Site-Selective and Stereoselective Intramolecular (2π + 2π) Photocycloaddition of Arylalkenes to Pyrene and Its Photocycloreversion

✍ Scribed by Maeda, Hajime; Sugimoto, Akira; Mizuno, Kazuhiko


Book ID
127241163
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
72 KB
Volume
2
Category
Article
ISSN
1523-7060

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Stereospecific (2π+2π) photocycloadditio
✍ Kazuhiko Mizuno; Hajime Maeda; Yohtaro Inoue; Akira Sugimoto; Luc P Vo; Richard 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 116 KB

Irradiation of benzene solutions containing pyrene and electron-de®cient arylalkenes such as E-and Zmethyl cinnamates aorded (2p+2p) photocycloadducts including 1:2-cycloadduct in high yields in a stereospeci®c and endo-selective manner. Sandwich-type singlet exciplexes between pyrene and arylalkene