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Site Occupancy Wave and Unprecedented Infinite Zigzag (Te2−2)nChains in the Flat Te Nets of the New Ternary Rare Earth Telluride FamilyALn3Te8

✍ Scribed by Rhonda Patschke; Joy Heising; Jon Schindler; Carl R. Kannewurf; Mercouri Kanatzidis


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
348 KB
Volume
135
Category
Article
ISSN
0022-4596

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✦ Synopsis


The three isostructural compounds CsCe 3 Te 8 , RbCe 3 Te 8 , and KNd 3 Te 8 were synthesized from the reaction of elemental copper and lanthanides in a molten alkali metal/polytelluride flux. They crystallize in the monoclinic space group P2 1 /a (No. 14) with a ‫؍‬ 9.057(2) A s ,