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Site-Isolation Effects in a Dendritic Nickel Catalyst for the Oligomerization of Ethylene

✍ Scribed by Müller, Christian; Ackerman, Lily J.; Reek, Joost N. H.; Kamer, Paul C. J.; van Leeuwen, Piet W. N. M.

Book ID
120414902
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
98 KB
Volume
126
Category
Article
ISSN
0002-7863

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The interaction of the olefin oligomerization catalyst system derived from [Ni(sacsac)(PBu,)CI] (sacsac = pentane-2,4-dithionate = dithioacetylacetonate) with carbon monoxide (CO) has been examined by a combination of ,'P NMR and FTIR spectroscopy. The catalyst is rapidly and completely inhibited by