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Site-Differentiated Hexanuclear Rhenium(III) Cyanide Clusters [Re 6 Se 8 (PEt 3 ) n (CN) 6- n ] n -4 ( n = 4, 5) and Kinetics of Solvate Ligand Exchange on the Cubic [Re 6 Se 8 ] 2+ Core

โœ Scribed by Gray, Thomas G.; Holm, R. H.

Book ID
126057748
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
145 KB
Volume
41
Category
Article
ISSN
0020-1669

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R1 โ€ซุโ€ฌ 0.0387, wR2 โ€ซุโ€ฌ 0.0624), (Pr 4 N) 2 Mn(H 2 O) 4 [Re 6 S 8 (CN) 6 ] (space group: I4/m, a โ€ซุโ€ฌ 13.255(2) A s , c โ€ซุโ€ฌ 14.432(3) A s , V โ€ซุโ€ฌ 2535.6(8) A s 3 , R1 โ€ซุโ€ฌ 0.0369, wR2 โ€ซุโ€ฌ 0.0960) and (Pr 4 N) 2 Ni (H 2 O) 4 [Re 6 S 8 (CN) 6 ] (space group: I4/m, a โ€ซุโ€ฌ 13.247(4) A s , c โ€ซุโ€ฌ 14.246(6) A