Sisyphus cooling of electrically trapped polyatomic molecules
✍ Scribed by Zeppenfeld, Martin; Englert, Barbara G. U.; Glöckner, Rosa; Prehn, Alexander; Mielenz, Manuel; Sommer, Christian; van Buuren, Laurens D.; Motsch, Michael; Rempe, Gerhard
- Book ID
- 118017180
- Publisher
- Nature Publishing Group
- Year
- 2012
- Tongue
- English
- Weight
- 616 KB
- Volume
- 491
- Category
- Article
- ISSN
- 0028-0836
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## Abstract Coupled and uncoupled Hartree–Fock theories are used to compute the electric dipole polarizability of water, ammonia, and methane with three different GTO basis sets. Bounds for the geometric approximation to uncoupled polarizabilities are also computed to examine the accuracy of calcul
Hartree-Fock perturbation theory is employed to compute electric dipole hyperpolarizabilities ofwater, ammo& and methane with three different CT0 basis sets. The results were extremely sensitive to the form of zero-order HT; wavefunctions. In mrne cases large discrepancies between computed and exper