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SiO2 Catalysed expedient synthesis of [E]-3-alkenoic acids in dry media

✍ Scribed by H.M.Sampath Kumar; B.V.Subba Reddy; E.Jagan Reddy; J.S. Yadav

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 189 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00113-6

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✦ Synopsis

Aliphatic aldehydes with ct-hydrogens and malonic acid undergo decarboxylative condensation on the surface of SiO 2 when subjected to microwave irradiation generating 13"/-unsaturated acids in high yields.

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