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Sintering characteristics of microfine zirconia powder

โœ Scribed by Jiang Xing -Xiang; Huang Dong -Shen; Weng Luqian


Publisher
Springer
Year
1994
Tongue
English
Weight
465 KB
Volume
29
Category
Article
ISSN
0022-2461

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โœฆ Synopsis


In this paper the sintering characteristics of yttria-doped zirconia microfine powder are investigated by measuring shrinkage and shrinkage rate curves of powder compacts. The experimental results show that there is a transition point in the shrinkage-temperature curves and two peaks appear in the shrinkage rate-temperature curves. These results provide further support for the idea that the sintering of microfine zirconia powders is a two-stage process. In the first stage, sintering of the powder compact is mainly dominated by inner-sintering in agglomerates and in the second stage, sintering will occur among densified agglomerates. The microstructure of agglomerates during sintering is also studied by TEM and provides evidence that the transition point in the shrinkage-temperature curve is the end of the first sintering stage. Furthermore, the relationships between sintering characteristics and powder parameters are investigated. It is found that the shrinkage rate in the first stage is related to the primary grain size of the powder, and in the second stage it is related to agglomerate size. The effect of agglomerates on the sinterability of microfine ZrO2 powder can be directly evaluated by the difference of shrinkage rate between the two sintering stages. Experiments also show that the shrinkage rate can be influenced by heating rate. A rapid heating rate would result in difficulties in the second sintering.stage.


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Zirconia powders with different types of stabiliser (Y 2 O 3 , Dy 2 O 3 and Yb 2 O 3 ) have been air plasma sprayed onto metallic substrates. The coatings were detached and dimensional changes during heat treatment were measured by dilatometry. Ytterbia-stabilised specimens exhibited the highest rat