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Singlets, triplets, and exciplexes: complex, temperature-dependent emissions from (2,9-dimethyl-1,10-phenanthroline)bis(triphenylphosphine)copper(1+) and (1,10-phenanthroline)(triphenylphosphine)copper(1+)

✍ Scribed by Palmer, Cynthia E. A.; McMillin, David R.

Book ID: 121432381
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 541 KB
Volume: 26
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00270a004

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The anisotropy of the triplet sublevel populating rates was determined for 1 , 1 0-phenanthroline ( phen), 2,9dimethyl-1,l Ophenanthroline (2,9-Me2phen) and their zinc(H) complexes in rigid solutions and for ZnClz(2,9-Merphen) in the crystalline state at 77 K by a time-resolved EPR technique. The su