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Singlet-triplet absorption spectra of azoalkanes

โœ Scribed by J. Metcalfe; S. Chervinsky; I. Oref

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
303 KB
Volume
42
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The sin$ct-triplet absorption spectra of truns-azo-methane, truns-azo-ethane, trawls-azo-n-propane, and trans-azo-isopropane have been measured using the technique of oxygen perturbation. It was found that the triplet level lies 55.5 + 1.5 kcal mole-' above the ground state in these compounds. These results are compared with other measurements of the triplet energes of acyclic azo-compounds and the relevance of this energy to their phctochemistry is discussed.

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