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Singlet excited-state “energy hopping” in alkylbenzenes

✍ Scribed by H. Morrison; G. Pandey

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
206 KB
Volume
96
Category
Article
ISSN
0009-2614

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✦ Synopsis

The quenching of toluene fluorescence b?: cir-6-phenyl-2-helene has been studied to determine the rate of singlet "energy hopping" in dilute solutions of alkylbenzenes. The singlet lifetime data have been analyzed by the Stem-Volmer method to give the quasi-isoenergeticrate, X-q, as 1.2 X 10 lo M-1 s-l_ This result is consistent with an escimer formationdlssoclation mechanism for alkylaromatic singlet energy transfer in dilute solution.

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