A well resolved spectrum h;ls been obtained for the pyrenc escimer in dcoxygenatcd cyclohexanc using modulation escitation spcctrophotometry.
Singlet excited monomer and excimer absorptions of pyrene
โ Scribed by M.F.M Post; J Langelaar; J.D.W van Voorst
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 713 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The absorption and polarization spectra from the first excited singlet state of pyrene and the absorption spectrum of the pyrene excimer are presented. These results were obtained by laser flash spectroscopy using a frequency doul bled ruby laser pulse of 6 nanoseconds halfwidth.
A qualitative preliminary assignment of the bands is given.
๐ SIMILAR VOLUMES
The absorption spectrum of the pyrene excimer in a single crystal has been measured. The spectrum is similar to that obtained in solution. The polarization of the absorption peaks in the crystal was found to be similar to that of the excimer fluorescence emission. The overlap between the excimeric e
An absorption spectrum attributable to the transition from the first excited singlet state to higher singlet states (S' Q--S transition) of pgrene in soIution has been observed by the flash method.