Sin& vibronic Ievel fluorescence spectra from four levels of the first excited singlet state of sulphur dioside are presented. mey are assigned in terms of rather short progressions in the two totally symmetric vibrations for stretching b,) and bending (ui)\_ The relative intensities observed presen
Single vibronic level fluorescence. V. Pyridazine
β Scribed by A.D. Jordan; C.S. Parmenter
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 428 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Resonance fluorescence has been observed from pyridazine vapour at 0.1 torr by exciting low energy bands in the 3700 A a3soprtion system with tuned light. Some spectra are shown and tl;eir analyses are diccussed. The fluorescence generated by pumping the band al 26 649 cm-' (vacuum) is consistent with its assignment as the 'BI-'AI electronic origin, but the structure of fluorescence after pumping a neighbouring absorption band sugests some modification of earlier proposals concerning excited state Fermi resonances in pyridazine.
π SIMILAR VOLUMES
Siie vibronic Ieve fb~orescence spectra of pyrazine4t~ and 44 are reported and the intensity distriiutions of tile Ione btg mode in these spectra are analyzed in terms of a vibronic coupling model.
In respon:e to a personal inquiry we have reesamined the pressure dependencu of the lifetime of three cscited vibronic states of SO\*. The new measurements confirm the old ones, in particular the observation that the cross section for self-quenching is very large. A possible interpretation of the ob