Immortal ring-opening polymerization of
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Clémence Guillaume; Jean-François Carpentier; Sophie M. Guillaume
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Article
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2009
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Elsevier Science
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English
⚖ 437 KB
The zinc alkoxide complex prepared in situ from the reaction of (BDI)Zn(N(SiMe 3 ) 2 ) is an efficient catalyst for both the solution and bulk ring-opening polymerization (ROP) of racemic-bbutyrolactone (BBL). The controlled ''immortal'' ROP of BBL using the binary catalytic system (BDI)Zn(N(SiMe 3