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Single-Site β-Diiminate Zinc Catalysts for the Ring-Opening Polymerization of β-Butyrolactone and β-Valerolactone to Poly(3-hydroxyalkanoates)

✍ Scribed by Rieth, Lee R.; Moore, David R.; Lobkovsky, Emil B.; Coates, Geoffrey W.


Book ID
120622144
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
233 KB
Volume
124
Category
Article
ISSN
0002-7863

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The zinc alkoxide complex prepared in situ from the reaction of (BDI)Zn(N(SiMe 3 ) 2 ) is an efficient catalyst for both the solution and bulk ring-opening polymerization (ROP) of racemic-bbutyrolactone (BBL). The controlled ''immortal'' ROP of BBL using the binary catalytic system (BDI)Zn(N(SiMe 3