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Single-site catalysts for olefin polymerization:: Annual review for 1997

✍ Scribed by Gregory G Hlatky

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
992 KB
Volume
199
Category
Article
ISSN
0010-8545

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✦ Synopsis

Papers, patents, and published patent applications from 1997 on olefin polymerization by single-site catalysts and processes in which they are used are reviewed. Included are disclosures on cocatalyst preparation, and the copolymerization of a-olefins and carbon monoxide by metal complexes.

πŸ“œ SIMILAR VOLUMES

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This review covers research in olefin polymerization by metallocene catalysts published in 1996. While metallocenes are generally defined as metal complexes with two cyclopentadienyl rings, this review will additionally cover catalysts containing only one cyclopentadienyl ring, as well as catalysts

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## Abstract A series of new neutral allyl Group 3 metal complexes bearing __ansa__‐bridged fluorenyl/cyclopentadienyl ligands [{Flu‐EMe~2~‐(3‐R‐Cp)}Ln(Ξ·^3^‐C~3~H~5~)(THF)] (E=C, R=H, Ln=Y (2), La (3), Nd (4), Sm (5); R=__t__Bu, Ln=Y (8), Nd (9); E=Si, R=H, Ln=Y (12), Nd (13)) were synthesized in go