𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Single-pellet cell for the measurement of intraparticle diffusion and convection

✍ Scribed by Z. P. Lu; J. M. Loureiro; A. E. Rodrigues


Publisher
American Institute of Chemical Engineers
Year
1992
Tongue
English
Weight
644 KB
Volume
38
Category
Article
ISSN
0001-1541

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Dynamic analysis of single‐pellet cell for the measurement of diffusion and convection in porous catalysts is revisited. A complete mathematical model for the “diffusion‐convection” cell is solved, and the relation between zero‐and first‐order moments of the cell response and operating parameters is derived. The validity region of the “simplified” boundary condition at the bottom of the pellet is quantified. The effect of the operating parameters on the cell time response to a tracer impulse is analyzed to check the practical range of operation of the system. It also is compared with the chromatographic technique.


📜 SIMILAR VOLUMES


The Use of Sample Rotation for Minimizin
✍ Nuria Esturau; Francesc Sánchez-Ferrando; José Adrián Gavin; Christian Roumestan 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 144 KB

Undesirable temperature gradients in a NMR sample tube are usually generated by an inappropiate temperature regulation system. We have shown that such convection effects can greatly distort the measurement of translational self-diffusion coefficients. The use of sample spinning helps to minimize suc

An approach for the optimization of tran
✍ Weiruo Sun; Fernão D. Magalhães; Carlos A. V. Costa 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 598 KB

## Abstract In a diffusion cell experiment, the presence of a film diffusion resistance, in series with intrapellet diffusion, leads to loss of precision in the estimation of intrapellet diffusivities. A general strategy, extendable to other problems, for quantifying a parametric region where film

Investigation of additional convective t
✍ H. Müller; G. Müller-Vogt 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB 👁 1 views

## Abstract Diffusion measurements of metallic and semiconductor melts on earth show highly irreproducible results due to occurrence of unknown convection. Therefore we investigated the influence of different kinds of additional transports. Diffusion experiments with the shear cell technique and nu