Single-Molecule Magnets with Mesomorphic Lamellar Ordering
β Scribed by Emmanuel Terazzi; Cyril Bourgogne; Richard Welter; Jean-Louis Gallani; Daniel Guillon; Guillaume Rogez; Bertrand Donnio
- Book ID
- 102724298
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 799 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract The reaction of [Mn~6~O~2~(Piv)~10~(4βMeβpy)~2.5~(PivH)~1.5~] (1) (py: pyridine, Piv: pivilate) with __N__βmethyldiethanolamine (mdeaH~2~) and Ln(NO~3~)~3~β 6βH~2~O in MeCN leads to a series of nonanuclear compounds [Mn~5~Ln~4~(O)~6~(mdea)~2~(mdeaH)~2~(Piv)~6~(NO~3~)~4~(H~2~O)~2~]β 2βMeCN
Due to the large intrinsic magnetic anisotropy of the lanthanide ions, rare-earth metal systems, and in particular dysprosium (Dy) based materials, have sparked increasing interest in the area of molecular magnetism. [1] In a molecular complex, when such a unique property is combined with a high-spi