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Single-molecule magnets based on iron(iii) oxo clusters

✍ Scribed by Gatteschi, Dante; Sessoli, Roberta; Cornia, Andrea


Book ID
115450640
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
843 KB
Volume
9
Category
Article
ISSN
1359-7345

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In search of 3d/4f-metal single-molecule
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The importance of 3d/4f-metal cluster chemistry is outlined, and the employment of 2-pyridyl ketone- and 2-pyridyl oxime-based ligands for the preparation of low-nuclearity Ni^II^/Ln^III^ complexes (Ln = lanthanide) is reviewed. The synthetic utility of the β€œmetal complexes as ligands” and β€œone-pot”