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Single-Molecule Imaging of Rotaxanes Immobilized on Glass Substrates: Observation of Rotary Movement

✍ Scribed by Dai Nishimura; Yoshinori Takashima; Hiroyuki Aoki; Toshiaki Takahashi; Hiroyasu Yamaguchi; Shinzaburo Ito; Akira Harada

Book ID
102722929
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
552 KB
Volume
120
Category
Article
ISSN
0044-8249

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## Abstract Peculiar ‘reptational’ movements of isotactic PMMA chains on mica are observed by in situ AFM. The polymer molecules comprise long flexible chains that exhibit reptative, or snake‐like, motion on the substrate along the direction of the polymer chain. Intriguingly, some chains underwent