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Single electron transfer induced total synthesis of canthin-6-one

✍ Scribed by Ulrich Rößler; Siegfried Blechert; Eberhard Steckhan

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 175 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01472-0

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✦ Synopsis

The cytotoxic alkaloid canthin-6-one was synthesized from harmalane in a short sequence (six steps) with good overall yield (18%) using a single electron transfer (SET) induced radical cationic hetero [4+2] cycloaddition as high yielding key step.

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