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Single electron transfer in the reaction of an alkyl iodide with LiAlH4 and LiAlD4 in the absence of a halogen atom radical chain process

โœ Scribed by E.C. Ashby; Catherine O. Welder; Fabio Doctorovich


Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
218 KB
Volume
34
Category
Article
ISSN
0040-4039

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Evidence for single electron transfer in
โœ E.C. Ashby; J.N. Argyropoulos ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

Evidence for a radical process in the reaction of the lithium enolate of propiophenone with a primary alkyl iodide was obtained by the observation of cyclization of an appropriate radical probe, by the trapping of the radical intermediate and by the comparison of the relative rates of reactions of t