Single crystal synthesis of higher-order sulfohalogenides in the temperature gradient: Bi19S27Br3, Bi2Cu3S4Br, Pb1−xBi2+xCu4−xS5I2

ChemInform Abstract: Local and Permeatin

ChemInform Abstract: Local and Permeating Disorder of Copper(I) Cations in Cu3BiS2Br2 and Cu4Bi3S5Br3-xClx (x = 1.19)

✍ Andreas Heerwig; Fabian Nitsche; Michael Ruck 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 22 KB 👁 1 views

Local and Permeating Disorder of Copper(I) Cations in Cu 3 BiS 2 Br 2 and Cu4Bi3S5Br3-xClx (x = 1.19) -Cu3BiS2Br2 (I) and Cu4Bi3S5Br1.81Cl1.19 (II) are synthesized from stoichiometric mixtures of Cu, Bi2S3, S, CuCl, NaCl, and CuBr (silica ampules, 570 °C, 14 d) and characterized by powder and single