Single Crystal Study of ClOO. Matrix Effects in the ESR and IR Spectra of ClOO Trapped in KClO4
โ Scribed by Byberg, J. R.
- Book ID
- 120355310
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 618 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
Ph~3~ร sBr is trapped in an Xโirradiated single crystal of Ph~3~As^+^CH~3~Br^โ^. The gโtensor, the ^75^As and ^79^Br magnetic hyperfine tensors and the ^79^Br quadrupolar interaction tensor are obtained at room temperature. They show that the structure of this arsoranyl radical is intermediate betwee
The study of the temperature dependenw of N and H atom dipolar coupling tensors of the radical SO$+J+Hz trapped in rirradfated sx&mic acid singIe crystals alfows a complete description of the potential well hindering the reorientations of the l@H, group. This potential weIl may be described by the e
Tfre (CZGD~)-J'~" radid is gtoduced by tbe X-irradtition of a single crystal of [C~Ds)3'3C-H. The principal values of the hyperfรญne couplรฌng with the r3C in the methyl positรญon are determined as Tl = 168 MHz, T2 = 24 MHz, \_ = 19 MHz. The corresponding spin density is compaxed witb thc values obtain
## The preparation of vitamin B12b single crystals doped wtth pammagnetic Bit, is described--rrom preliminary ESR data the orientation of B12T with respect to the crysttilogmphic axes system of Bllb is determined. The linewxdth depending on \_-temperature, orientation and tni, wII be discussed. Th